TS EAMCET 2023 DELETED SYLLABUS(30 PERCENT) MPC&BiPC

 TS EAMCET 2023 

DELETED SYLLABUS(30 PERCENT)&

REMAINING SYLLABUS(70 PERCENT)

MPC&BiPC

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70% Syllabus for TS EAMCET 2023-MPC (Engineering Stream)

The syllabus is in tune with the syllabus adapted by the Board of Intermediate Education,TS

For Intermediate course with effect from the academic year 2021-2022 (1st year) (70%) and 2022-2023 (2nd year) (100%) and is designed at the level of Intermediate Course and equivalent to (10+2) scheme of Examination conducted by Board of Intermediate Education, TS.

The syllabus is designed to indicate the scope of subjects included for TS EAMCET-2023. 

The topics mentioned therein are not to be regarded as exhaustive. Questions may be asked in TS EAMCET-2023 to test the student’s knowledge and intelligent understanding of the subject.

The syllabus is applicable to students of both the current and previous batches of Intermediate Course, who desire to appear for TS EAMCET-2023.

70% MATHS Syllabus for TS EAMCET 2023 

1)ALGEBRA

a)Functions: Types of functions - Definitions - Real Valued functions (Domain, Range).

b)Matrices: Types of matrices – Scalar multiple of a matrix and multiplication of

matrices – Transpose of a matrix – Determinants (up to 3.4.7) – Adjoint and Inverse of

a matrix – Solution of simultaneous linear equations – Cramer’s Rule, Matrix Inversion

Method.

c)Complex Numbers: Complex number as an ordered pair of real numbers

- fundamental operations - Representation of complex numbers in the form 𝑎 + 𝑖𝑏, Modulus and amplitudes of complex number-illustrations. Geometrical and polar representation of complex number in Argand plane – Argand Diagram.

d)De Moivre’s Theorem: De Moivre’s theorem- Integral and Rational indices - n th

roots of unity- Geometrical Interpretations – Illustrations.

e)Quadratic Expressions: Quadratic expressions, equations in one variable - Sign of

quadratic expressions – Change in signs and Maximum and minimum values, Quadratic inequations

f)Theory of Equations: The relation between the roots and coefficients in an equation -

Solving an equation when two or more of its roots are connected by certain relations -

Equations with real coefficients - occurrence of complex roots in conjugate pairs and

its consequences - Transformation of equations - Reciprocal Equations.

g)Permutations and Combinations: Fundamental Principle of counting – linear and

circular permutations - Permutations of ‘n’ dissimilar things taken ‘r’ at a time -

Permutations when repetitions are allowed, Circular permutations, Permutations with

constraint repetitions - Combinations – definitions and certain theorems.

h)Binomial Theorem: Binomial theorem for positive integral index - Binomial theorem

for rational Index - Approximations using Binomial Theorem.

i)Partial fractions: Rational functions - Partial fractions of f(x)/g(x) when g(x) contains

non-repeated linear factors - Partial fractions of f(x)/g(x) when g(x) contains repeated

and/or non-repeated linear factors - Partial fractions of f(x)/g(x) when g(x) contains

irreducible factors.

2) TRIGONOMETRY:

a)Trigonometric Ratios up to Transformations: Trigonometric ratios - variation -

Graphs and Periodicity - Trigonometric ratios of Compound angles - Trigonometric

ratios of multiple and sub-multiple angles - Sum and Product transformations.

b)Hyperbolic Functions: Definition of Hyperbolic Functions - Graphs - Addition

formulae of Hyperbolic Functions.

c)Properties of Triangles: Relation between sides and angles of a Triangle - Sine,

Cosine and Tangent Rules - Projection Rules - Half angle formulae and area of a

triangle - Incircle and excircles of a Triangle.

3)VECTOR ALGEBRA:

a)Addition of Vectors: Vectors as a triad of real numbers, some basic concepts -

Classification (Types) of vectors – Sum (Addition) of vectors - Scalar multiplication of

a Vector - Angle between two non-zero vectors - Linear combination of vectors -

Component of a vector in Three Dimensions - Vector Equations of Line and Plane.

b)Product of Vectors: Scalar or dot Product of two vectors - Geometrical Interpretation- Orthogonal projections - Properties of dot product - Expression of scalar (dot) product,Angle between two vectors - Geometrical Vector methods - Vector equations of plane in normal form - Angle between two planes Vector product (cross product) of two vectors and properties - Vector product in (𝑖,𝑗, 𝑘) system - Vector Areas - Scalar Triple Product.

4) PROBABILITY:

a)Measures of Dispersion: 

Range - Mean deviation - Variance and standard deviation of ungrouped / grouped data - Coefficient of Variation and analysis of frequency

distributions with equal means but different variances.

b)Probability: 

Random experiments and events - Classical definition of probability,

Axiomatic approach and addition theorem of probability - Independent and dependent

events - Conditional probability - Multiplication theorem and Baye’s Theorem.

c)Random Variables and Probability Distributions: Random Variables - Theoretical

discrete distributions – Binomial and Poisson Distributions.

5)COORDINATE GEOMETRY:

a)Locus: Definition of Locus-Illustrations -Equation of Locus -Problems connected to

it.

b)Transformation of Axes: Transformation of axes - Rules, derivations and illustrations-Rotation of axes-Derivations - Illustrations.

c)The Straight Line: Revision of fundamental results - Straight line - Normal form -

Illustrations - Straight line - Symmetric form - Straight line - Reduction into various

forms - Intersection of two Straight Lines - Family of straight lines - Concurrent lines -

Condition for Concurrent lines - Angle between two lines - Length of the perpendicular from a point to a Line - Distance between two parallel lines - Concurrent lines-properties related to a triangle.

d)Pair of Straight lines: Equations of a pair of lines passing through the origin - Angle

between a pair of lines - Condition for perpendicular and coincident lines, bisectors of

angles - Pair of lines - second degree general equation

- Homogenizing a second

-degree equation with a first-degree equation in 𝑥 and 𝑦.

e)Circle: Equation of a circle, standard form, center and radius - Position of a point in

the plane of a circle - Definition of a tangent - Position of a straight line in the plane of

a circle - Conditions for a line to be tangent - Chord of contact and polar - Relative

positions of two circles.

f)System of circles: Angle between two intersecting circles - Radical axis of two circles.

g)Parabola: Conic sections - Equation of tangent and normal at a point on the parabola.

h)Ellipse: Equation of ellipse in standard form, Parametric equations - Equation of

tangent and normal at a point on the ellipse.

i)Hyperbola: Equation of hyperbola in standard form - Parametric equations, Equation

of tangent and normal at a point on the hyperbola.

j)Three Dimensional Coordinates: Coordinates - Section formulae.

k)Direction Cosines and Direction Ratios: Direction Cosines - Direction Ratios.

l)Plane: Cartesian equation of Plane - Simple Illustrations.

6)CALCULUS:

a)Limits: Intervals and neighbourhoods - Limits - Standard Limits.

b)Differentiation: Derivative of a function - Elementary Properties - Trigonometric,

Hyperbolic - Derivatives - Methods of Differentiation.

c)Applications of Derivatives: Errors and approximations - Geometrical Interpretation

of the derivative - Equations of tangents and normal to a Curve - Angles between two

curves and condition for orthogonality of curves - Maxima and Minima.

d)Integration: Integration as the inverse process of differentiation, Standard forms and properties of integrals - Method of substitution - Integration of Algebraic, Exponential,Logarithmic, Trigonometric and Inverse trigonometric functions - Integration -Partial  fractions method - Reduction formulae.

e)Definite Integrals: Definite Integral as the limit of sum - Interpretation of Definite

Integral as an area - The Fundamental theorem of Integral Calculus – Properties -

Reduction formulae - Applications of definite integral to areas.

f)Differential equations: Formation of Differential Equation - Degree and order of an

Ordinary Differential Equation - Solving Differential Equation - By Variables separable method, Homogeneous Differential Equations, Non-Homogeneous Differential Equations and Linear Differential Equations.

70% PHYSICS Syllabus for TS EAMCET 2023

1) PHYSICAL WORLD: 

What is physics? Fundamental forces in nature.

2) UNITS AND MEASUREMENTS: 

Introduction, The international system of units,

Measurement of Length, Measurement of Large Distances, Estimation of Very Small

Distances: Size of a Molecule, Range of Lengths, Measurement of Mass, Range of Masses,

Measurement of time, Accuracy, precision of instruments and errors in measurement,

Systematic errors, random errors, least count error, Absolute Error, Relative Error and

Percentage Error, Combination of Errors, Significant figures, Rules for Arithmetic

Operations with Significant Figures, Rounding off the Uncertain Digits, Rules for

Determining the Uncertainty in the Results of Arithmetic Calculations, Dimensions of

Physical Quantities, Dimensional Formulae and dimensional equations, Dimensional

Analysis and its Applications, Checking the Dimensional Consistency of Equations,

Deducing Relation among the Physical Quantities.

3) MOTION IN A STRAIGHT LINE: 

Introduction, Position, path length and displacement,

Average velocity and average speed, Instantaneous velocity and speed, Acceleration.

Kinematic equations for uniformly accelerated motion, Relative velocity.

4) MOTION IN A PLANE: 

Introduction, Scalars and vectors, Position and Displacement

Vectors, Equality of Vectors, Multiplication of vectors by real numbers, Addition and

subtraction of vectors - graphical method, Resolution of vectors, Vector addition -

analytical method, Motion in a plane, Position Vector and Displacement, Velocity,

Acceleration, Motion in a plane with constant acceleration, Relative velocity in two

dimensions. Projectile motion, Equation of path of a projectile, Time of Maximum height,

Maximum height of a projectile, Horizontal range of projectile, Uniform circular motion.

5) LAWS OF MOTION: 

Introduction, Conservation of momentum, Equilibrium of a particle,

Common forces in mechanics, friction, Circular motion, Motion of a car on a level road,

Motion of a car on a Banked Road, Solving problems in mechanics.

6) WORK, ENERGY AND POWER: 

Introduction, The Scalar Product, Notions of work and kinetic energy : The work-energy theorem, Work, Kinetic energy, Work done by a variable force, The work-energy theorem for a variable force, The concept of Potential Energy, The conservation of Mechanical Energy, The Potential Energy of a spring, Various forms of energy: the law of conservation of energy, Heat, Chemical Energy, Electrical Energy, The Equivalence of Mass and Energy, Nuclear Energy. The Principle of Conservation of Energy, Power, Collisions, Elastic and Inelastic Collisions, Collisions in one dimension, Coefficient

of Restitution and its determination, Collisions in Two Dimensions.

7) SYSTEMS OF PARTICLES AND ROTATIONAL MOTION:

Introduction, What kind of motion can a rigid body have?, Centre of mass, Centre of Gravity, Motion of centre of mass, Linear momentum of a system of particles, Vector product of two vectors, Angular

velocity and its relation with linear velocity, Angular acceleration, Kinematics of rotational

motion about a fixed axis, Torque and angular momentum, Moment of force (Torque),

Angular momentum of particle, Torque and angular momentum for a system of a particles,

conservation of angular momentum, Equilibrium of a rigid body, Principle of moments,

Moment of inertia, Dynamics of rotational motion about a fixed axis, Angular momentum 

in case of rotation about a fixed axis, Conservation of Angular Momentum, Rolling motion,

Kinetic Energy of Rolling Motion.

8) OSCILLATIONS: 

Introduction, Periodic and oscillatory motions, Period and frequency,

Displacement, Simple harmonic motion (S.H.M.), Simple harmonic motion and uniform

circular motion, Velocity and acceleration in simple harmonic motion, Force law for Simple

harmonic Motion, Energy in simple harmonic motion, Some systems executing Simple

Harmonic Motion, Oscillations due to a spring, The Simple Pendulum, Damped simple

harmonic motion, Forced oscillations and resonance.

9) GRAVITATION: 

Introduction, Universal law of gravitation, Acceleration due to gravity

below and above the surface of earth, Gravitational potential energy, Escape speed, Earth

satellite, Energy of an orbiting satellite, Geostationary and polar satellites, Weightlessness.

10) MECHANICAL PROPERTIES OF SOLIDS: 

Introduction, Elastic behaviour of solids,

Stress and strain, Hooke’s law, Stress-strain curve, Elastic moduli, Young’s Modulus, Bulk

Modulus.

11) MECHANICAL PROPERTIES OF FLUIDS: 

Introduction, Pressure, Pascal’s Law,

Variation of Pressure with Depth, Atmosphere Pressure and Gauge Pressure, Hydraulic

Machines, Streamline flow, Bernoulli’s principle, Speed of Efflux: Torricelli’s Law,

Venturi-meter, Blood Flow and Heart Attack, Dynamic Lift. Viscosity, Variation of

Viscosity of fluids with temperature, Stokes’ Law, Reynolds number, critical velocity,

Surface tension, Surface Energy, Surface Energy and Surface Tension, Angle of Contact,

Drops and Bubbles, Capillary Rise, Detergents and Surface Tension.

12) THERMAL PROPERTIES OF MATTER: 

Introduction, Temperature and heat,

Measurement of temperature, Ideal-gas equation and absolute temperature, Thermal

expansion. Specific heat capacity, Calorimetry, Change of state, Regelation, Latent Heat,

Black body Radiation, Greenhouse Effect, Newton’s law of cooling.

13)THERMODYNAMICS:

Introduction, Thermal equilibrium, Zeroth law of thermodynamics, Heat, Internal Energy and work, First law of thermodynamics, Specific

heat capacity. Thermodynamic state variables and equation of State, Thermodynamic

process, Quasi-static process, Isothermal Process, Adiabatic Process, Isochoric Process,

Isobaric process, Cyclic process, Second law of thermodynamics, Reversible and irreversible

processes.

14) KINETIC THEORY:

Introduction, Molecular nature of matter, Behavior of gases, Boyle’s

Law, Charles’ Law, Kinetic theory of an ideal gas, Pressure of an Ideal Gas, kinetic

interpretation of temperature, Law of equipartition of energy, Specific heat capacity,

Monatomic Gases, Diatomic Gases, Polyatomic Gases, Specific Heat Capacity of Solids,

Specific Heat Capacity of Water, Mean free path.

15) WAVES: 

Introduction, Transverse and longitudinal waves, Displacement relation in a

progressive wave, The speed of a travelling wave, The principle of superposition of waves,

Reflection of waves, Beats, Doppler Effect.

16) RAY OPTICS AND OPTICAL INSTRUMENTS: 

Introduction, Reflection of light by

Spherical Mirrors, Refraction, Total Internal Reflection, Refraction at Spherical Surfaces and 

by Lenses, Refraction through a Prism, Dispersion by a Prism, Some Natural Phenomena due

to Sunlight, The Rainbow, Scattering of light, Optical Instruments.

17) WAVE OPTICS: 

Introduction, Huygens Principle, Refraction and reflection of plane waves

using Huygens Principle, Coherent and Incoherent Addition of Waves, Interference of Light

Waves and Young’s Experiment, Diffraction, The single slit, seeing the single slit diffraction

pattern, Resolving power of optical instruments, The validity of ray optics, Polarization.

18) ELECTRIC CHARGES AND FIELDS: 

Introduction, Electric Charges, Conductors and

Insulators, Charging by Induction, Basic Properties of Electric Charge, Coulomb’s Law, Forces

between Multiple Charges, Electric Field, Electric Field Lines, Electric Flux, Electric Dipole,

Dipole in a Uniform External Field, Continuous Charge Distribution, Gauss’s Law,

Application of Gauss’s Law, Field due to an infinitely long straight uniformly charged wire,

Field due to a uniformly charged infinite plane sheet, Field due to a uniformly charged thin

spherical shell.

19) ELECTROSTATIC POTENTIAL AND CAPACITANCE: 

Introduction, Electrostatic

Potential, Potential due to a Point Charge, Potential due to an Electric Dipole, Potential due to

a System of Charges, Equipotential Surfaces, Potential Energy of a System of Charges,

Potential Energy in an External Field, Electrostatics of Conductors, Dielectrics and

Polarisation, Capacitors and Capacitance, The Parallel Plate Capacitor, Effect of Dielectric on

Capacitance, Combination of Capacitors, Energy Stored in a Capacitor, Van de Graaf generator

20) CURRENT ELECTRICITY: 

Introduction, Electric Current, Electric Currents in Conductors,

Ohm’s law, Drift of Electrons and the Origin of Resistivity, Limitations of Ohm’s Law,

Resistivity of various Materials, Temperature Dependence of Resistivity, Electrical Energy,

Power, Combination of resistors-series and parallel, Cells, emf, Internal Resistance, Cells in

Series and in Parallel, Kirchhoff’s rules, Wheatstone Bridge, Meter Bridge, Potentiometer.

21) MOVING CHARGES AND MAGNETISM: 

Introduction, Magnetic Force, Motion in a

Magnetic Field, Motion in combined electric and magnetic fields, Magnetic Field due to a

Current Element, Biot-Savart Law, Magnetic Field on the Axis of a Circular Current Loop,

Ampere’s Circuital Law, The Solenoid and the Toroid, Force between Two Parallel Currents,

the Ampere, Torque on Current Loop, Magnetic Dipole, The Moving Coil Galvanometer.

22) MAGNETISM AND MATTER:

Introduction, The Bar Magnet, The magnetic field lines, Bar

Magnet as a equivalent solenoid, The dipole in a uniform magnetic field, The Electrostatic

analog, Magnetism and Gauss’s Law, The Earth’s Magnetism, Magnetisation and Magnetic

Intensity, Magnetic properties of materials, Permanent magnets and electromagnets.

23) ELECTROMAGNETIC INDUCTION: 

Introduction, The Experiments of Faraday and

Henry, Magnetic Flux, Faraday’s Law of Induction, Lenz’s Law and Conservation of Energy,

Motional Electromotive Force, Energy Consideration: A Quantitative Study, Eddy Currents,

Inductance, AC Generator.

24) ALTERNATING CURRENT: 

Introduction, AC Voltage Applied to a Resistor,

Representation of AC Current and Voltage by Rotating Vectors — Phasors, AC Voltage

Applied to an Inductor, AC Voltage Applied to a Capacitor, AC Voltage Applied to a Series

LCR Circuit, Power in AC Circuit: The Power Factor, LC Oscillations, Transformers.

25) ELECTROMAGNETIC WAVES: 

Introduction, Displacement Current, Electromagnetic

Waves, Electromagnetic Spectrum.

26) DUAL NATURE OF RADIATION AND MATTER: 

Introduction, Electron Emission,

Photoelectric Effect, Experimental Study of Photoelectric Effect, Photoelectric Effect and

Wave Theory of Light, Einstein’s Photoelectric Equation, Energy Quantum of Radiation,

Particle Nature of Light: The Photon, Wave Nature of Matter, Davisson and Germer

Experiment.

27) ATOMS: 

Introduction, Alpha-particle Scattering and Rutherford’s Nuclear Model of Atom,

Atomic Spectra, Bohr Model of the Hydrogen Atom, The Line Spectra of the Hydrogen Atom,

DE Broglie’s Explanation of Bohr’s Second Postulate of Quantisation.

28) NUCLEI: 

Introduction, Atomic Masses and Composition of Nucleus, Size of the Nucleus,

Mass-Energy and Nuclear Binding energy, Nuclear Force, Radioactivity, Nuclear Energy.

29) SEMICONDUCTOR ELECTRONICS: MATERIALS, DEVICES AND SIMPLE

CIRCUITS: 

Introduction, Classification of Materials: Metals, Semiconductors and Insulators,

Intrinsic Semiconductor, Extrinsic Semiconductor, p-n Junction, Semiconductor diode,

Application of Junction Diode as a Rectifier, Special Purpose p-n Junction Diodes, Zener

diode, optoelectronic junction devices, Junction Transistor, transistor structure and action,

basic transistor circuit configurations and transistor characteristics, Transistor as a device,

Transistor as an amplifier (CE configuration), Feedback amplifier and transistor oscillator

Digital Electronics and Logic Gates, Integrated Circuits.

30) COMMUNICATION SYSTEMS: 

Introduction, Elements of a Communication System,

Basic Terminology Used in Electronic Communication Systems, Bandwidth of Signals,

Bandwidth of Transmission Medium, Propagation of Electromagnetic Waves, Modulation

and its Necessity, Amplitude Modulation, Production of Amplitude Modulated Wave,

Detection of Amplitude Modulated Wave. 

70% CHEMISTRY Syllabus for TS EAMCET 2023

1) ATOMIC STRUCTURE:

Developments leading to the Bohr’s model of atom; Wave nature of electromagnetic radiation;

Particle nature of electromagnetic radiation- Planck’s quantum theory; Dual behaviour of

matter; Bohr’s model for Hydrogen atom; Explanation of line spectrum of hydrogen;

Limitations of Bohr’s model; Quantum mechanical considerations of sub atomic particles;

Heisenberg’s uncertainty principle; Quantum numbers; Energies of orbitals; Filling of orbitals

in atoms. Aufbau Principle, Pauli’s exclusion Principle and Hund’s rule of maximum

multiplicity; Electronic configurations of atoms; Stability of half-filled and completely filled

orbitals.

2) CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES:

Modern periodic law and present form of the periodic table; Nomenclature of elements with

atomic number greater than 100; Electronic configuration of elements and the periodic table;

Electronic configuration and types of elements s, p, d and f blocks; Trends in physical

properties: (a) Atomic radius, (b) Ionic radius (c) Ionization enthalpy, (d) Electron gain

enthalpy, (e) Electronegativity; Periodic trends in chemical properties: (a) Periodicity of

valence or Oxidation states, (b) Anomalous properties of second period elements - diagonal

relationship; Periodic trends and chemical reactivity.

3) CHEMICAL BONDING AND MOLECULAR STRUCTURE:

Kossel - Lewis approach to chemical bonding, Octet rule, covalent bond-Lewis representation

of simple molecules, formal charges, limitations of octet rule; Ionic or electrovalent bond -

Crystal structure of sodium chloride, Lattice enthalpy; General properties of ionic compounds;

Bond Parameters - bond length, bond angle, bond enthalpy, bond order, resonance - Polarity

of bonds - dipole moment; Fajan’s rules; Valence Shell Electron Pair Repulsion (VSEPR)

theory; Predicting the geometry of simple molecules; Valence bond theory-Orbital overlap

concept-Directional properties of bonds-overlapping of atomic orbitals, strength of sigma and

pi bonds-Factors favouring the formation of covalent bonds; Hybridisation- different types of

hybridization involving s, p and d orbitals- shapes of simple covalent molecules; Coordinate

bond -definition with examples; Molecular orbital theory - Formation of molecular orbitals,

Linear combination of atomic orbitals (LCAO)-conditions for combination of atomic orbitals

- Energy level diagrams for molecular orbitals -Bonding in some homo nuclear diatomic

molecules- H2, He2, Li2, B2, C2, N2 and O2; Hydrogen bonding-cause of formation of hydrogen

bond - Types of hydrogen bonds-inter and intra molecular-General properties of hydrogen

bonds.

4) STATES OF MATTER: GASES AND LIQUIDS:

Intermolecular forces; Thermal Energy; Intermolecular forces vs Thermal interactions; The

Gaseous State; The Gas Laws; Ideal gas equation; Graham’s law of diffusion; Dalton’s Law of

partial pressures; Kinetic molecular theory of gases; Kinetic gas equation of an ideal gas (No

derivation) deduction of gas laws from Kinetic gas equation; Behaviour of real gases -

Deviation from Ideal gas behaviour - Compressibility factor vs Pressure diagrams of real gases.

5) STOICHIOMETRY:

Importance of chemistry-some basic concepts - Properties of matter - uncertainty in

measurement-significant figures, dimensional analysis; Atomic and molecular masses- mole

concept and molar mass. Concept of equivalent weight; Percentage composition of compounds

and calculations of empirical and molecular formulae of compounds; Stoichiometry and 

stoichiometric calculations; Redox reactions-classical idea of redox reactions, oxidation and

reduction reactions-redox reactions in terms of electron transfer; Oxidation number concept;

Types of Redox reactions-combination, decomposition, displacement and disproportionation

reactions; Balancing of redox reactions - oxidation number method, Half reaction (ion

electron) method.

6) THERMODYNAMICS:

Thermodynamic Terms; The system and the surroundings; Types of systems and surroundings;

The state of the system; The Internal Energy as a State Function. (a) Work (b) Heat (c) The

general case, the first law of Thermodynamics; Applications-Work; Enthalpy- a useful new

state function; Extensive and intensive properties; Measurement of U and H: Calorimetry;

Enthalpy change, rH of reactions - reaction Enthalpy (a) Standard enthalpy of reactions, (b)

Enthalpy changes during phase transformations, (c) Standard enthalpy of formation, (d)

Thermo chemical equations (e) Hess’s law of constant heat summation; Enthalpies for different

types of reactions. (a) Standard enthalpy of combustion (∆cH ), (b) Enthalpy of atomization

(∆aH ), phase transition, sublimation and ionization, (c) Bond Enthalpy (∆bondH ), (d) Enthalpy

of solution (∆solH ) and dilution; Lattice enthalpy Spontaneity. (a) Is decrease in enthalpy a

criterion for spontaneity (b) Entropy and spontaneity, the second law of thermodynamics, (c)

Gibbs Energy and spontaneity; Absolute entropy and the third law of thermodynamics.

7) CHEMICAL EQUILIBRIUM AND ACIDS-BASES:

Equilibrium in Physical processes; Equilibrium in chemical processes - Dynamic Equilibrium;

Law of chemical Equilibrium - Law of mass action and Equilibrium constant; Homogeneous

Equilibria, Equilibrium constant in gaseous systems. Relationship between KP and Kc;

Heterogeneous Equilibria; Applications of Equilibrium constant; Factors affecting Equilibria -

Le Chatelier’s principle - application to industrial synthesis of Ammonia and Sulphur trioxide;

Ionic Equilibrium in solutions; Acids, bases and salts- Arrhenius, Bronsted-Lowry and Lewis

concepts of acids and bases; Buffer solutions-designing of buffer solution-Preparation of

Acidic buffer; Solubility Equilibria of sparingly soluble salts. Solubility product constant,

Common ion effect on solubility of ionic salts.

8) HYDROGEN AND ITS COMPOUNDS:

Position of hydrogen in the periodic table; Dihydrogen-Occurrence and Isotopes; Hydrides:

Ionic, covalent, and non-stoichiometric hydrides; Water: Physical properties; structure of

water, ice. Chemical properties of water; hard and soft water, temporary and permanent

hardness of water; Heavy Water; Hydrogen as a fuel.

9) s - BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

Group 1 Elements: Alkali metals; Electronic configurations; Atomic and Ionic radii;

Ionization enthalpy; Hydration enthalpy; Physical properties; Chemical properties; Uses;

General characteristics of the compounds of the alkali metals: Oxides; Halides; Salts of oxo

acids; Anomalous properties of Lithium: Differences and similarities with other alkali metals,

Diagonal relationship; similarities between Lithium and Magnesium;

Group 2 Elements: Alkaline earth elements; Electronic configuration; Ionization enthalpy;

Hydration enthalpy; Physical properties, Chemical properties; Uses; General characteristics of

compounds of the Alkaline Earth Metals: Oxides, hydroxides, halides, salts of oxoacids

(Carbonates; Sulphates and Nitrates); Anomalous behavior of Beryllium; its diagonal

relationship with Aluminium. 

10) p- BLOCK ELEMENTS GROUP 13 (BORON FAMILY):

General introduction - Electronic configuration, Atomic radii, Ionization enthalpy, Electro

negativity; Physical & Chemical properties; Important trends and anomalous properties of

boron.

11) p-BLOCK ELEMENTS - GROUP 14 (CARBON FAMILY):

General introduction - Electronic configuration, Atomic radii, Ionization enthalpy, Electro

negativity; Physical & Chemical properties; Important trends and anomalous properties of

carbon; Allotropes of carbon; Uses of carbon.

12) ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES, TECHNIQUES AND

HYDROCARBONS

SOME BASIC PRINCIPLES AND TECHNIQUES

General introduction; Tetravalency of Carbon: shapes of organic compounds; Structural

representations of organic compounds; Classification of organic compounds; Nomenclature of

organic compounds; Isomerism; Fundamental concepts in organic reaction mechanisms;

Fission of covalent bond; Nucleophiles and electrophiles; Electron movements in organic

reactions; Electron displacement effects in covalent bonds: inductive effect, resonance,

resonance effect, electromeric effect, hyperconjugation; Types of Organic reactions.

HYDROCARBONS

Classification of Hydrocarbons; Alkanes - Nomenclature, isomerism (structural and

conformations of ethane only); Preparation of alkanes; Properties - Physical properties and

chemical reactivity, Controlled Oxidation, Isomerization, Aromatization, reaction with steam;

Alkenes - Nomenclature, structure of ethene, Isomerism (structural and geometrical); Methods

of preparation; Properties- Physical and chemical reactions: Addition of hydrogen, halogen,

water, sulphuric acid, hydrogen halides (Mechanism- ionic and peroxide effect,

Markovnikov’s, anti Markovnikov’s or Kharasch effect). Oxidation, Ozonolysis and

Polymerization.

Alkynes - Nomenclature and isomerism, structure of acetylene. Methods of preparation of

acetylene; Physical properties, Chemical reactions- acidic character of acetylene, addition

reactions- of hydrogen, Halogen, Hydrogen halides and water. Polymerization.

Aromatic Hydrocarbons: Nomenclature and isomerism, Structure of benzene, Resonance and

aromaticity; Preparation of benzene. Physical properties. Chemical properties: Mechanism of

electrophilic substitution. Electrophilic substitution reactions - Nitration, Sulphonation,

Halogenation, Friedel-Crafts alkylation and acylation; Directive influence of functional groups

in mono substituted benzene; Carcinogenicity and toxicity.

13) SOLID STATE:

General characteristics of solid state; Amorphous and crystalline solids; Classification of

crystalline solids based on different binding forces (molecular, ionic, metallic and covalent

solids); Probing the structure of solids: X-ray crystallography; Crystal lattices and unit cells.

Number of atoms in a unit cell (primitive, body centred and face centred cubic unit cell);

Close packed structures: Close packing in one dimension, in two dimensions and in three

dimensions- tetrahedral and octahedral voids- formula of a compound and number of voids

filled - locating tetrahedral and octahedral voids; Packing efficiency in simple cubic, bcc,

hcp, ccp lattice; Calculations involving unit cell dimensions-density of the unit cell;

Imperfections in solids-types of point defects-stoichiometric and non-stoichiometric defects.

Electrical properties, Magnetic properties (Band theory of metals, conductors, semiconductors

and insulators and n and p type semiconductors)

14) SOLUTIONS:

Types of solutions; Expressing concentration of solutions - mass percentage, volume

percentage, mass by volume percentage, parts per million, mole fraction, molarity and molality;

Solubility: Solubility of a solid in a liquid, solubility of a gas in a liquid, Henry’s law; Vapour

pressure of liquid solutions: vapour pressure of liquid- liquid solutions. Raoult’s law as a

special case of Henry’s law - vapour pressure of solutions of solids in liquids; Ideal and non

ideal solutions; Colligative properties and determination of molar mass-relative lowering of

vapour pressure-elevation of boiling point-depression of freezing point-osmosis and osmotic

pressure-reverse osmosis and water purification; Abnormal molar masses-van’t Hoff

factor.

15) ELECTROCHEMISTRY AND CHEMICAL KINETICS:

ELECTROCHEMISTRY:

Electrochemical cells, Galvanic cells; Nernst equation-equilibrium constant from Nernst

equation- electro chemical cell and Gibbs energy of the cell reaction; Conductance of

electrolytic solutions- measurement of the conductivity of ionic solutions-variation of

conductivity and molar conductivity with concentration-strong electrolytes and weak

electrolytes-applications of Kohlrausch law; Electrolytic cells; Electrolysis: Faraday’s laws

of electrolysis-products of electrolysis; Batteries: primary and secondary batteries, Fuel cells,

Corrosion of metals-Hydrogen economy

CHEMICAL KINETICS: Rate of a chemical reaction; Factors influencing rate of a reaction:

dependance of rate on concentration- rate expression and rate constant- order of a reaction,

molecularity of a reaction; Integrated rate equations-zero order reactions-first order

reactions- half-life of a reaction; Pseudo first order reaction; Temperature dependence of the

rate of a reaction. Effect of catalyst, Collision theory of chemical reaction rates.

16) SURFACE CHEMISTRY:

Adsorption and absorption: Distinction between adsorption and absorption-mechanism of

adsorption; types of adsorption; characteristics of physisorption; characteristics of

chemisorption; adsorption isotherms; adsorption from solution phase; applications of

adsorption

Catalysis: catalysis, homogeneous and heterogeneous, Adsorption theory of heterogeneous

catalysis, activity and selectivity of solid catalysis, Shape - selective catalysis by zeolites,

Enzyme catalysis, Catalysis in industry.

Colloids; Classification of colloids: Classification based on physical state of dispersed phase

and dispersion medium- classification based on nature of interaction between dispersed phase

and dispersion medium- classification based on type of particles of the dispersed phase- multi

molecular, macromolecular and associated colloids- cleansing action of soaps-preparation of

colloids-purification of colloidal solutions- properties of colloidal solutions: Tyndall effect,

colour, Brownian movement-charge on colloidal particles, electrophoresis. Coagulation or

precipitation, Coagulation of lyophilic sols, protection of colloids, Colloids around us -

applications of colloids.

Emulsions – types of emulsions

17) GENERAL PRINCIPLES OF METALLURGY:

Occurance of metals, Concentration of ores - levigation, magnetic separation, froth floatation,

leaching, Extraction of crude metal from concentrated ore-conversion to oxide, reduction of

oxide to the metal, Thermodynamic principles of metallurgy-Ellingham diagram-limitations

applications-extraction of iron, copper and zinc from their oxides; Electrochemical principles 

`of metallurgy, Oxidation and reduction, Refining of crude metal-distillation, liquation, poling,

electrolysis, zone refining and vapour phase refining; Uses of aluminium, copper, zinc and iron

18) p-BLOCK ELEMENTS:

GROUP-15 ELEMENTS: Introduction - Occurrence- electronic configuration, atomic and

ionic radii, ionisation enthalpy, electronegativity, physical and chemical properties;

Dinitrogen-preparation, properties and uses; Compounds of nitrogen-preparation, properties

and uses of ammonia; Oxides of nitrogen; preparation, properties and uses of nitric acid;

Phosphorous-allotropic forms, Phosphine-preparation, properties and uses, Phosphorous

halides, Oxoacids of phosphorous.

GROUP-16 ELEMENTS: Introduction - Occurrence- electronic configuration, atomic and

ionic radii, ionisation enthalpy, electron gain enthalpy, electronegativity, physical and

chemical properties; Dioxygen-preparation, properties and uses; Simple oxides: Ozone -

preparation, properties, structure and uses; Sulphur allotropic forms; Sulphur dioxide

preparation, properties and uses; Oxoacids of sulphur; Sulphuric acid-Properties and uses only,

Sulphuric acid-manufacture.

GROUP-17 ELEMENTS: Introduction - Occurrence, electronic configuration, atomic and

ionic radii, ionisation enthalpy, electron gain enthalpy, electronegativity, physical and chemical

properties; Chlorine- preparation, properties and uses; Hydrogen chloride- preparation,

properties and uses; Oxoacids of halogens; Interhalogen compounds.

GROUP-18 ELEMENTS: Introduction - Occurrence, electronic configuration, ionization

enthalpy, atomic radii, electron gain enthalpy, physical and chemical properties (a) Xenon

fluorine compounds- XeF2, XeF4 and XeF6 -preparation, hydrolysis and formation of fluoro

anions-structures of XeF2, XeF4 and XeF6 (b) Xenon-oxygen compounds XeO3 and XeOF4 -

their formation, structures and uses.

19) d AND f BLOCK ELEMENTS & COORDINATION COMPOUNDS:

d AND f BLOCK ELEMENTS: Position in the periodic table; Electronic configuration of

the d-block elements; General properties of the transition elements (d-block) - physical

properties, variation in atomic and ionic sizes of transition series, ionisation enthalpies,

oxidation states, trends in the M²+/M and M³+/M²+ standard electrode potentials, trends

in stability of higher oxidation states, chemical reactivity and Eθ values, magnetic properties,

formation of coloured ions, formation of complex compounds, catalytic properties, formation

of interstitial compounds, alloy formation; Some important compounds of transition elements;

Inner transition elements, Actinoids; Some applications of d and f block elements.

COORDINATION COMPOUNDS: Werner’s theory of coordination compounds;

Definitions of some terms used in coordination compounds; Nomenclature of

coordination compounds-IUPAC nomenclature; Isomerism in coordination compounds -

(a)Stereo isomerism-Geometrical and optical isomerism (b)Structural isomerism-linkage,

coordination, ionisation and hydrate isomerism; Bonding in coordination compounds.

(a)Valence bond theory - magnetic properties of coordination compounds-limitations of

valence bond theory (b) Crystal field theory (i) Crystal field splitting in octahedral and

tetrahedral coordination entities (ii) Colour in coordination compounds-limitations of crystal

field theory; Bonding in metal carbonyls; Stability of coordination compounds; Importance and

applications of coordination compounds. 

20) POLYMERS

Classification of Polymers -Classification based on source, structure, mode of polymerization,

molecular forces and growth polymerization

Types of polymerization reactions-addition polymerization or chain growth polymerization

ionic polymerization, free radical mechanism-preparation of addition polymers-polythene,

teflon and poly acrylonitrile; condensation polymerization or step growth polymerization

polyamides-preparation of Nylon 6,6 and nylon 6-poly esters-terylene-bakelite, melamine,

formaldehyde polymer-copolymerization-Rubber-natural rubber-vulcanisation of rubber

Synthetic rubbers-preparation of neoprene and buna-N

Molecular mass of polymers-number average and weight average molecular masses- poly

dispersity index (PDI)

Biodegradable polymers-PHBV, Nylon 2-nylon 6

Polymers of commercial importance-poly propene, poly styrene, poly vinyl chloride (PVC),

urea-formaldehyde resin, glyptal, bakelite- their monomers, structures and uses

21) BIOMOLECULES:

Carbohydrates - Classification of carbohydrates-Monosaccharides: preparation of glucose

from sucrose and starch- Properties and structure of glucose- D, L and (+), (-) configurations

of glucose - Structure of fructose; Disaccharides (sucrose, lactose, maltose), polysaccharides

(starch, cellulose, glycogen); importance of carbohydrates.

Amino acids: Natural amino acids-classification of amino acids - structures and D and L

forms-Zwitterions.

Proteins: Structures, classification, fibrous and globular- primary, secondary, tertiary and

quaternary structures of proteins- Denaturation of proteins.

Nucleic acids: Chemical composition of nucleic acids, structures of nucleic acids, DNA

finger printing, biological functions of nucleic acids.

Enzymes: Enzymes, mechanism of enzyme action.

Vitamins and Hormones.

22) CHEMISTRY IN EVERYDAY LIFE:

Drugs and their classification: (a) Classification of drugs on the basis of pharmacological

effect (b) Classification of drugs on the basis of drug action (c) Classification of drugs on the

basis of chemical structure (d) Classification of drugs on the basis of molecular targets.

Drug-Target interaction-Enzymes as drug targets (a) Catalytic action of enzymes (b) Drug

enzyme interaction; Receptors as drug targets.

Therapeutic action of different classes of drugs: antacids, antihistamines, neurologically

active drugs: tranquilizers, non-narcotic analgesics, narcotic analgesics, antimicrobials

antibiotics, antiseptics and disinfectants- antifertility drugs.

Chemicals in food: Artificial sweetening agents, food preservatives, antioxidants in food.

Cleansing agents-soaps and synthetic detergents.

23) HALOALKANES AND HALOARENES:

Classification and nomenclature; Nature of C-X bond; Methods of preparation: Alkyl halides

and aryl halides-from alcohols, from hydrocarbons (a) by free radical halogenation (b) by

electrophilic substitution (c) by replacement of diazonium group (Sandmeyer reaction) (d)

by the addition of hydrogen halides and halogens to alkenes-by halogen exchange

(Finkelstein reaction); Physical properties-melting and boiling points, density and solubility;

Chemical reactions: Reactions of haloalkanes (i) Nucleophilic substitution reactions (a) SN²

mechanism (b) SN¹ mechanism (c) stereochemical aspects of nucleophilic substitution

reactions-optical activity (ii) Elimination reactions (iii) Reaction with metals-Reactions of 

halo arenes: (i) Nucleophilic substitution (ii) Electrophilic substitution and (iii) Reaction with

metals. Polyhalogen compounds.

24) ORGANIC COMPOUNDS CONTAINING C, H AND O (Alcohols, Phenols, Ethers,

Aldehydes, Ketones and Carboxylic acids):

ALCOHOLS, PHENOLS AND ETHERS

Alcohols, phenols and ethers - classification; Nomenclature: (a) alcohols, (b) phenols and (c)

ethers; Structures of hydroxy and ether functional groups; Methods of preparation:

Alcohols from alkenes and carbonyl compounds (reduction and reaction with Grignard

reagents).

Phenols from haloarenes, benzene sulphonic acid, diazonium salts, cumene;

Physical properties of alcohols and phenols; Chemical reactions of alcohols and phenols

(i) Reactions involving cleavage of O-H bond-Acidity of alcohols and phenols, esterification

(ii) Reactions involving cleavage of C-O bond- reactions with HX, PX3, dehydration and

oxidation (iii) Reactions of phenols- electrophilic aromatic substitution, Kolbe’s reaction,

Reimer - Tiemann reaction, reaction with zinc dust, oxidation.

Ethers-Methods of preparation: By dehydration of alcohols, Williamson synthesis

Physical properties-Chemical reactions: Cleavage of C-O bond and electrophilic substitution

of aromatic ethers, Some Commercially important alcohols (uses with special reference to

methanol and ethanol).

ALDEHYDES AND KETONES

Nomenclature and structure of carbonyl group; Preparation of aldehydes and ketones-

(1) by oxidation of alcohols (2) by dehydrogenation of alcohols (3) from hydrocarbons -

Preparation of aldehydes (1) from acyl chlorides (2) from nitriles and esters (3) from

hydrocarbons-Preparation of ketones (1) from acyl chlorides (2)from nitriles (3)from benzene

or substituted benzenes; Physical properties of aldehydes and ketones; Chemical reactions of

aldehydes and ketones-nucleophilic addition, reduction, oxidation, reactions due to alpha

hydrogen and other reactions (Cannizzaro reaction, electrophilic substitution reaction); Uses

of aldehydes and ketones.

CARBOXYLIC ACIDS

Nomenclature and structure of carboxyl group; Methods of preparation of carboxylic

acids (1) from primary alcohols and aldehydes (2) from alkyl benzenes (3)from nitriles

and amides (4) from Grignard reagents (5) from acyl halides and anhydrides (6) from esters;

Physical properties; Chemical reactions: (i) Reactions involving cleavage of O-H bond-acidity,

reactions with metals and alkalies (ii) Reactions involving cleavage of C-OH bond-formation

of anhydride, reactions with PCl5, PCl3, SOCl2, esterification and reaction with ammonia (iii)

Reactions involving-COOH group-reduction, decarboxylation (iv) Substitution reactions

in the hydrocarbon part - halogenation and ring substitution; Uses of carboxylic acid.

25) ORGANIC COMPOUNDS CONTAINING NITROGEN:

AMINES

Structure of amines; Classification; Nomenclature; Preparation of amines: reduction of nitro

compounds, ammonolysis of alkyl halides, reduction of nitriles, reduction of amides, Gabriel

phthalimide synthesis and Hoffmann bromamide degradation reaction; Physical properties;

Chemical reactions: basic character of amines, alkylation, acylation, carbyl amine reaction,

reaction with nitrous acid, reaction with aryl sulphonyl chloride, electrophilic substitution

of aromatic amines-bromination, nitration and sulphonation.

DIAZONIUM SALTS

Methods of preparation of diazonium salts, Physical properties, Chemical reactions.

Importance of diazonium salts in synthesis of aromatic compounds.

CYANIDES AND ISOCYANIDES

Structure and nomenclature of cyanides and isocyanides, Preparation, physical properties and

chemical reactions of cyanides and isocyanides.

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